Keeping your cool isn’t easy for batteries or fuel cells

If batteries are 95% efficient, and therefore hardly generate any heat, why do they sometimes suffer from overheating and shortened lifetime? And why do fuel cell cars like the Toyota Mirai (pictured above) have such huge radiator grills? To explain these questions we’ll take a very simple look at efficiency and heat transfer. To a scientist “efficient” is basically synonymous with “doesn’t produce much waste heat”, and all waste heat needs to be sent into the environment (rejected) to avoid overheating.

Let’s use cars as an example.

The following graph compares three hypothetical vehicles, each of them delivering the same 100 kW (133 hp) of brake power. The combustion engine requires the input of 500 kW of gasoline chemical energy, converts 20% of it to mechanical power, and loses the other 80% as waste heat. The battery vehicle uses about 118 kW of battery chemical energy to deliver the same 100 kW brake power, so it only needs to get rid of 18 kW of heat. A fuel cell system is about 50% efficient so rejects 100 kW of heat.

graph1

Why does the battery vehicle have any heat issues if its produces so few kilowatts of waste heat? The reason has to do with the fact lithium-ion batteries have a relatively narrow operating range. While combustion engines can handle temperatures from -30°C to 110°C, and fuel cells about -20°C to 80°C, Li-ion batteries should not be run hotter than 55°C. Higher temperatures shorten battery life and reduce performance.

graph2

The difference between 55°C, 80°C, and 110°C doesn’t sound like a lot. But the problem comes on hot summer days, where the ambient air cooling the engine, fuel cell, or battery may be 40°C or hotter. As engineers know, it’s temperature difference that transfers heat. The difference between a hot engine at 110°C and 40°C is substantial, but a 55°C battery is only 15°C hotter than the environment, which means battery electric vehicles still need effective cooling systems (high surface area radiators, good fans, etc.). To show this visually, the colored area on the graph below is the available temperature difference for each of these technologies on a hot 40°C day:

graph3

Fuel cells have the same issue – only 100 kW of waste heat, but it needs to be rejected across a 40°C temperature difference, which is why fuel cell cars have such large radiators and air intakes despite having only a quarter of the waste heat of a combustion engine. (And that’s why a lot of work goes into developing special radiators and higher-temperature fuel cells).

from NOVA

Honda FCX and its multiple radiators – from NOVA

This brief dip into thermodynamics explains why efficient technologies like batteries and fuel cells may still require a great deal of cooling. But it’s just the tip of the iceberg (so to speak) for cooling of advanced power systems, though – there are many other interesting topics:

  • When to use air cooling vs. liquid cooling
  • The effect of solar heating on a parked car or battery backup system. 1 kW/m^2 of solar energy can be a significant heating load
  • The amount of waste heat that is carried away by a combustion engine’s exhaust gases
  • How to heat a fuel cell or battery from -40°C to its minimum operating temperature
  • How to trade off insulating a fuel cell or battery from cold weather, vs. the risk of overheating during hot weather

Bonus chart – same data as above but in a single graph. The area of each circle is proportional to waste heat.

temperature-vs-efficiency

One thought on “Keeping your cool isn’t easy for batteries or fuel cells

  1. Great article! It clearly explains the confusing situation of needing to cool efficient systems like electric vehicles.

    Maybe an interesting addition to the discussion could be on the future of battery and fuel cell cooling. Are there any promising new materials or techniques that might allow for more efficient heat transfer or higher operating temperatures for batteries?

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